Thanks for your patience. The metallurgist has confirmed my suspicions. The steel is plated.
That is why the lab results differ from the XRF results.
We were interested in identifying the steel alloy the semi-cyindrical artifact is made of. We have multiple XRF readings but we wondered if they might be "polluted" by contaminants on the surface of the artifact, so Rick Freeman took a small piece that had broken off the artifact and ground it down until he could see bare, shiny metal. In so doing, he inadvertently ground off the plating, so what the lab analyzed was the base steel minus the plating. What the XRF was seeing is the base metal, plus the plating, plus a layer of paint.
The base metal is carbon steel allied with a little manganese.
Based on averages of the XRF readings, the plating is:
Tin 4.587%
Zinc 1.407%
Manganese 0.458% (minus the manganese in the steel alloy)
Copper 0.394%
Cobalt 0.736%
Chromium 0.129%
Molybdenum 0.125%
Vanadium 0.125%
The paint is:
Silicon 2.633%
Titanium 1.398%
Lead 0.129%
and maybe some of the Cobalt.
"Tin cans" are steel plated with tin as a corrosion inhibitor. They've been around since 1840. The tin plating on this artifact is much more complex than a can of peaches, but its purpose is the same. The paint added a further layer of protection. Whether or not it is part of the PL8's water tank, somebody really didn't want this thing to get rusty.
Nevertheless, the portion of this object that was exposed to the pond water corroded completely away over the decades.
What does that say about the survivability of other un-buried and mostly un-plated steel debris? No wonder our visual searches have found nothing.
- May 08, 2024, 11:27:56 AM
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